Separation of cobalt and nickel using solvent extraction with acidic organophosphorus compounds.
نویسندگان
چکیده
منابع مشابه
Separation of cobalt and nickel by solvent extraction with two mutually immiscible ionic liquids.
The proof-of-principle for the separation of metals by solvent extraction using two mutually immiscible ionic liquids is given. Cobalt was extracted from the ionic liquid 1-ethyl-3-methylimidazolium chloride to the ionic liquid trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate. A distribution ratio of 44 was obtained. Cobalt could be selectively separated from nickel, with a...
متن کاملSeparation of Nickel and Zinc Ions in a Synthetic Acidic Solution by Solvent Extraction Using D2ehpa and Cyanex 272
Solvent extraction was used to recover nickel and zinc from synthetic acidic solution. Many leaching solution and waste waters contain both zinc and nickel at the same time. Bis (2,4,4trimethylpentyl) phosphinic acid (Cyanex 272) and Di(2-ethylhexyl) phosphoric acid (D2EHPA) were used to separate nickel and zinc. In the D2EHPA system, at equilibrium pH of 2, zinc extraction was more than 98% wh...
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The potential use of synergistic mixtures of reagents for the solvent extraction of nickel (and cobalt) from lateritic leach liquors was pointed out in the early 1980s by Grinstead, who used dinonylnaphthalene sulphonic acid in conjunction with some 2-pyridyl compounds for the recovery of these metals from slightly acidic solutions1,2. Shortly thereafter, studies at Mintek revealed marked syner...
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Enantiomer separation of acidic compounds
CHIRALPAK QN-AX and QD-AX are anion exchanger chiral stationary phases providing specifi c enantioselectivity for acidic compounds. In this Application Note, we demonstrate that the application of these columns can be extended to supercritical fl uid chromatography (SFC) for enantiomer separation of acidic compounds. Using the advantages of the advanced technology of the Agilent 1260 Infi nity ...
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ژورنال
عنوان ژورنال: JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
سال: 1983
ISSN: 0021-9592,1881-1299
DOI: 10.1252/jcej.16.384